It may have been an on-screen-only wedding, but as this is probably the closest we'll ever get to a picture of Brad Pitt and Angelina Jolie at the altar, I think it definitely counts as an iconic bridal moment!
It is, of course, a still from the 2005 movie, Mr and Mrs Smith, in which Angie and Brad play married assassins hired to kill each other, and although Angelina probably didn't have much of a say in her character's wedding attire, I think the simple style of this white off-the-shoulder gown and short viel is exactly the kind of look she would go for as a bride. It certainly suits her, anyway - if only it were real!
Related: Angelina Jolie's 'Good Shepherd' wedding gown at Cherished Bride | Pick Angelina Jolie's wedding dress! | Angelina Jolie to get wedding dress from Goodwill?

From: Daily Frock: Suzanne Neville Antoinette